对氯气校正法测定高氯废水化学需氧量的方法研究

氯气校正法(HJ/T70-2001)是测定高氯废水化学需氧量的国标方法,为了减少样品测定过程带来的环境污染,研究在不改变HJ/T70-2001氧化体系及测试条件的情况下,将取样体积由20 mL减半为10 mL,试剂的使用量相应减半,对方法的检出限、相对误差、相对标准偏差等指标进行验证。结果表明,该方法的检出限符合要求,准确度较高,精密度较好,可用于高氯废水化学需氧量的测定。     

基于多孔环形喷嘴的可燃爆粉尘分散特征的密度效应研究*

为了研究不同密度的可燃爆粉尘在内置多孔环形喷嘴的20 L爆炸特性测试装置中的分散特征，基于负载粒子流方法、耦合DPM动量平衡方程和时间平均 Navier Stokes控制方程组，实现3种不同密度的煤粉、铝粉和锆粉在20 L爆炸测试装置中粉尘分散全过程的数值模拟。研究结果表明:多孔环形喷嘴的分散较为均匀，但是约束管道末端存在局部粉尘残留区，致使爆炸仓内真实粉尘浓度远低于形式浓度；爆炸仓中心位置的最大湍动能随着粉尘密度的增加而减小，只有显著地变化粉尘密度才能展示区分度较高的浓度峰值和抵达浓度峰值的时间。     

诱导喷嘴改进滤筒脉冲清灰效果的实验研究

改善清灰效果是提高滤筒除尘效率的关键和难点问题。运用自制脉冲喷吹实验台,采用诱导喷嘴(超音速引流喷嘴和气流散射器)对325 mm×660 mm滤筒进行脉冲喷吹清灰实验研究,并与采用普通喷吹孔的实验结果进行比较分析,得出采用诱导喷嘴时侧壁正压力峰值平均值是普通喷吹孔的1.465倍;且采用诱导喷嘴时各测点的不均衡系数为0.768～1.336,普通喷口为0.270～2.251,而不均衡系数越接近于1,其清灰效果越好;同时,采用诱导喷嘴时各测点基本在同一时刻达到正峰值。实验充分表明采用诱导喷嘴确保了滤筒长度方向上内壁清灰压力的均匀性,且对滤筒清灰效果有明显的改善作用。     

精细化工固定源废气采样时机的选择探讨

以某医药企业某产品生产过程为实例,综合各工段生产步骤、时间、废气产生情况及估算的污染物浓度等因素,绘制各污染因子排放规律图,从而确定各污染因子排放浓度(排放量)最大的1 h为最佳采样时机。     

Comparative study on effect of blending,thermal barrier coating (LHR) and injector nozzle geometry on biodiesel-fuelled engines

Increased petroleum prices, increased threat to the environment from exhaust emissions and global warming have generated intense international interest in developing renewable and alternative non-petroleum fuels for internal combustion engines. Evolving suitable technology for addressing energy crisis creates a continued investigation into the search for sustainable and clean-burning renewable fuels. This work investigates suitability of different non-edible-derived biodiesels such as cotton seed oil methyl ester (COME), Honne oil methyl ester (HnOME) and Rubber seed oil methyl ester (RuOME) to four stroke, single cylinder compression ignition (CI) engine. Engine tests were conducted to study the effect of fuel blending, thermal barrier coating (TBC) or Low Heat Rejection (LHR) and injector nozzle geometry on the performance, combustion and emission characteristics of COME, HnOME and RuOME in the modified CI engine. Blends of biodiesels with diesel were varied from 20 to 80% in steps of 20%. Two thermal barrier coatings of partially stabilized zirconium (PSZ) and aluminium oxide (Al₂O₃) were provided on the engine to make it fully adiabatic. Nozzle injectors of 3, 4 and 5 holes, with size of orifice varied from 0.2 to 0.3 mm size were selected for the study. It was concluded that B20 biodiesel blend, PSZ-coated engine and four hole nozzle injector of 0.2 mm size resulted in overall better engine performance with increased brake thermal efficiency (BTE) and reduced HC, CO, smoke emissions for the fuel combinations tested. Combustion analysis to study the effect of biodiesel blends, LHR coatings, injector nozzle geometry on the performance of the biodiesel-fuelled engine has been presented to give more insight into the behaviour of operation.     

Determination of 15 phthalate esters in air by gas-phase and particle-phase simultaneous sampling

Based on previous research, the sampling and analysis methods for phthalate esters (PAEs) were improved by increasing the sampling flow of indoor air from 1 to 4 L/min, shortening the sampling duration from 8 to 2 hr. Meanwhile, through the optimization of chromatographic conditions, the concentrations of 9 additional PAE pollutants in indoor air were measured. The optimized chromatographic conditions required a similar amount of time for analysis as before, but gave high responsivity, the capability of simultaneously distinguishing 15 kinds of PAEs, and a high level of discrimination between individual sample peaks, as well as stable peak generation. The recovery rate of all gas-phase and particle-phase samples of the 15 kinds of PAEs ranged from 91.26% to 109.42%, meeting the quantitative analysis requirements for indoor and outdoor air sampling and analysis. For the first time, investigation of the concentration levels as well as characteristics of 15 kinds of PAEs in the indoor air from four different traffic micro-environments (private vehicles, busses, taxis and subways) was carried out, along with validation of the optimized sampling and analytical method. The results show that all the 9 additional PAEs could be detected at relatively high pollution levels in the indoor air from the four traffic micro-environments. As none of the pollution levels of the 15 kinds of PAEs in the indoor air from the 4 traffic micro-environments should be neglected, it is of great significance to increase the types of PAEs able to be detected in indoor air.     

喷嘴直径对降尘效果影响的试验研究

为提高喷雾降尘效率,以改善作业环境,有必要研究喷嘴直径与降尘效果间的关系。基于自行设计的喷雾降尘试验系统,采用马尔文实时高速喷雾粒度分析仪、高速摄像仪及粉尘浓度测定仪对不同直径喷嘴的雾化特性参数和降尘效率进行测定。结果表明,在相同喷雾压力下,随着喷嘴直径的增大,全尘降尘效率持续增加,而呼吸性粉尘降尘效率先增加后减小,并在喷嘴直径为1.5 mm时达到最大值;在耗水量相同的情况下,随着喷嘴直径的增大,全尘和呼吸性粉尘降尘效率均下降。在井下喷雾降尘中,当耗水量不受限制时,为同时确保全尘和呼吸性粉尘降尘效率,宜选择直径为1.5 mm的喷嘴;当耗水量受限制时,宜选择直径为1.2 mm的喷嘴。     

火灾中闭式喷头响应时间的概率分布特性研究

喷淋系统中闭式喷头响应时间受火灾增长因子、径向安装距离和喷头响应时间指数等因素的影响。通过对喷头响应时间的模拟数据的统计分析,建立了包含火灾增长因子、径向距离和喷头响应时间指数等参数的喷头响应时间模型。考虑火灾增长因子和径向距离的随机性,获得了喷头响应时间的概率分布特性。研究结果表明,径向距离和火灾增长因子对喷头响应时间的分布特性影响显著。随着火灾增长因子的增大和径向距离的缩小,喷头在较短时间内响应的概率增大。随着径向距离的缩小,喷头响应时间指数对喷头响应时间分布的影响变小。研究可为优化喷头布置和评估喷头响应的有效性提供分析工具。     

A device for sampling the mud‐water interface in eutrophic lakes and bogs for residue analysis

Abstract

A tubular device has been developed making it possible to obtain layered samples of loosely aggregated, flocculent material from bogs or eutrophic lakes. The samples are up to 50 cm long and 15 cm in diameter. The sampler is free from protuberances and intact, layered samples can be taken. The tubular part of the sampler is about 85 em long, the walls of the lower 25‐cm portion harbouring a pneumatic closing mechanism which is controlled from above the water surface. An extendible handle for manipulating the sampler and for guiding it into place, is fastened to the upper end of the sampling tube. The performance and the operation of the sampler in the field are described.     

A soil sampling intercomparison exercise for the ALMERA network

Soil sampling and analysis for radionuclides after an accidental or routine release is a key factor for the dose calculation to members of the public, and for the establishment of possible countermeasures. The IAEA organized for selected laboratories of the ALMERA (Analytical Laboratories for the Measurement of Environmental Radioactivity) network a Soil Sampling Intercomparison Exercise (IAEA/SIE/01) with the objective of comparing soil sampling procedures used by different laboratories. The ALMERA network is a world-wide network of analytical laboratories located in IAEA member states capable of providing reliable and timely analysis of environmental samples in the event of an accidental or intentional release of radioactivity. Ten ALMERA laboratories were selected to participate in the sampling exercise. The soil sampling intercomparison exercise took place in November 2005 in an agricultural area qualified as a “reference site”, aimed at assessing the uncertainties associated with soil sampling in agricultural, semi-natural, urban and contaminated environments and suitable for performing sampling intercomparison. In this paper, the laboratories sampling performance were evaluated.